Carbon-Centered Radicals II by H. Fischer (auth.), H. Fischer (eds.)

By H. Fischer (auth.), H. Fischer (eds.)

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BonifaEik/Asmus Ref. p. 1 Absolute rate cotistants of displacefient Solvent C,H,CH, + CHJ(CH,),lSH Phot. / add. ref. 104M-‘s-‘3s) &H,cH, + (n-C,H,),SnH C,H,CH, + (n-C,H,)$n Laser flash phot. 105M-‘s-’ KAS 2,2,4-trimethylpentane RT 81 Cha 1 C,H,c(CH,), + CH,(CH,),,SH Phot. 103M-‘s-‘38) (C,H,),c + C,H,SH (&H,),CH + C,H$ Decomp. 9(6) kJ mol- 1 (C,H,),e + 2,4,6-(CH,),C,H,SH (&H,),CH + 2,4,6-(CH,),C,H$ Decomp. 6(293)Jmol-’ K-’ 38)Steady-state calculation. 3g)Photometricdeterminationof steady-stateradicalconcentration.

Add. ref. 10sM-‘s-‘45) (Uridine-S-monophosphate-OH’) 46) + HSCH,CH(NH,)COOH SCH,CH(NH,)COOH Pulse rad. 1 Radicals containing only C and H atoms eD, + CH,OH * CD,H + cH,OH + cD,cocD, --L CD, + CD,COCD, Phot. of acetone-d, PR CD,COCD,/ CH,OH e:H, + CBrCl, A CH,Br + &I, + Ccl, A CH,Cl + &l, Reduct. of CH,HgOCOCH, by NaBH, PR, glc ccl, e:H, + CBrCl, A CH,Br + &I, + C,H,CH, L CH, + C,H$H, Thermal decomp. of acetylperoxide PR, glc toluene e:H, + Ccl, a-, CH,Cl + &I, + C6H,CH3 --% CH, + C6H,eH2 Thermal decomp.

Of acetylperoxide olefine: methylethylketone 338 PR diethylmaleate, k,lk, diethylfumarate, ethylene glycolmaleic anhydride polyester, diethylmaleate, 358 diethylfumarate, ethylene glycolmaleic anhydride polyester, CH, + CH,CH,CH,COOH 8, CH, + n-butyric acid( + n-C,H,, -% CH, + n-heptane( -I$ Thermal decomp. of diacetylperoxide n-heptane 353 PR*‘) 333.. 363 CH, + (CH,),CHCOOH * CH, + (CH,),CCOOH + n-C,H,, b-, CH, + (t~-c,H;~) Therm. of acetylperoxide 353 PR26) n-C316 333.. 14. 56. -’ CH, + (CH,),CHCOOH 8, CH, + isobutyric acid( -A) + n-C,H r6 b, CH, + n-heptane( - I$ Thermal decomp.

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