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55. Symons M. , J. Chem. , part I, No. 10, pp. 3033-3044. 56. L, Trudy Instituta Khim. Nauk AN KazSSR, 1983, vol. 60, pp. 3 - 8 . (Rus) 57. Bekarek V. , 'Rozpoustedlove vlivy v chemii a jejch hodnoceni', Pokroky Chemii 23, Praha, 1992, Academia, p. 1725. 58. , J. Amer. Chem. Soc, 1985, vol. 107(1), pp. 1 - 1 1 . 59. Chastrette M. , Tetrahedron, 1982, vol. 1615 1618. 60. Chastrette M. , Canad. J. , 1985, vol. 63(12), pp. 3492 3498. 61. G. , Org. Reactivity, 1979, vol. 16(1), pp. 103 107. 22 Correlation Analysis In Chemistry Of Solutions Chapter 2.
3 9 ^ ^ - 9 . 0 8 ^ - ^ . e. 984 between E and Ej is observed. Therefore, for electrophilic substances these scales are adequate. That is why application of Ej scale is more desirable, because it is deduced in the experiment and possesses no calculation errors. The disadvantage of E scale is that for some substances values in it are negative, which has not been considered by the authors. This, for example, resulted in characterization of different substances by the same electron demand E = 0 (diethyl ether, benzene and nitrobenzene).
Primarily, in accordance with Gordy , the measure of solvent basicity was represented by OD band shift in the spectrum of methanol. Further on, this parameter was replaced by OH band shift in phenol IR-spectrum in the presence of appropriate donor in CCU solution compared with phenol dissolved in pure CCI4 because of high sensitivity of this value . The solvent ability to 30 Correlation Analysis In Chemistry Of Solutions electrophilic solvation is characterized by the Dimroth-Reiehardt parameter, Eh  improved by subtraction of nonspecific interaction influence in accordance with the following equation: £ = £ T - 2 5 .